Mark your calendars: Villarreal vs Napoli goes live on Tuesday, October 13, 2026 at 21:00 in what promises to be a thrilling UEFA Champions League. League phase encounter. Venue: Home Arena, Germany. Referee Robert Hartmann has been selected to oversee proceedings. The weather forecast reads: Cool and dry, 12°C. Key absences could shape this game — Werner is a concern for Villarreal, while Krause may miss out for Napoli. These two sides have a rich history: Napoli 4 - 3 Villarreal (2024). Napoli 2 - 4 Villarreal (2021). Napoli 3 - 2 Villarreal (2022). Napoli 0 - 3 Villarreal (2021). Napoli 2 - 1 Villarreal (2024). We're going with 1:2 as our predicted scoreline.